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The difference between "deglaze" and "flambé" is a dex check.
From: [identity profile] chenoameg.livejournal.com
Deglazing is: Using a solvent and high heat to get all of those yummy brown bits off the bottom of the pan after you've used it to sauté or brown something. It's a step in many pan sauces, for example. The Mailliard reaction (which I'm almost certainly misspelling) turns protein sweet and flavorful when you brown it.

The solvent is water-based, either water, or stock, or milk, or wine/spirits.

Additional trivia fact -- some flavor compounds are water-soluable. Some are fat-soluable. Some are alcohol-soluable. Using all three generates the most flavor. Tomato sauce is a particularly good example of this.

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